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I believe the idea behind it is that red it's the first color to disappear under water.
from Cajun Line co.
Cajun Lightning Filler Spools
When on the surface, the colored line looks like blood, convincing hungry predators to attack an easy meal. Cajun Lightning - "the line that acts like a lure™". Increase your strikes by up to 60%. Red is one of the first wavelengths to disappear under water, so this revolutionary line's blood-red color disappears within the first few feet of water, making it practically invisible for more strikes from the most line-shy fish.
as far as hooks being thin just check around you will find red hooks in almost any gauge and size you want.
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