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Using One Outlook profile - you can create a subfolder called "Work" or whatever under Inbox Tools -> Rules -> New Rule -> Start from Blank -> Check Arrive -> check "Thru Specified Account" & add the work e-mail -> next -> move it to "specified folder" and select folder
Second option and my personal favorite is to create multiple Outlook Profiles which will allow you to seperate the accounts as their own PST and contact lists
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