Sounds like it's been enabled to fire up at bootup via the registry. I don't know of an easy way to tell you how to fix this, but the gist of it is that you can download some type of "registry" clean/viewer and try to fix it yourself.
Be warned though, many a rookie has tried "editing" their registry only to blow their computer out of the water, and having to reinstall their computer.
I'm a big fan of reinstalling my computer every six months. Goddamn those spyware are always staying a step ahead of the curve on the ad-aware/spybot cleaners.
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