Pour some tomato juice in a bowl, and see if they will drink it.
I had a dog get sprayed in the face once. He swallowed some, and the smell just stayed with him. Then he started 'coughing' and the vet told me to get him to drink some.
The spray is kinda oily. so any acid will work. vinegar and water or tomato juice works great.
If the dog got it in the face, take your time and clean the ears well - that is where some lingering odor may stay trapped.
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