i may be wrong but OE does not use .pst files, those are specific to outlook.
go to this location on your hard drive (it wont be C: if your mounting as a slave.
C:\Documents and Settings\Shaun(whatever you profile name is)\Local Settings\Application Data\Identities\{03C43F01-97E6-45CF-B920-AB682DF6A808}(this will be different)\Microsoft\Outlook Express\
copy that folder off... and see if you can import the contents into ms mail.
hope that helps.
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