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Bryan's right about the fish-catching abilities - mono & fluorocarbon are neck & neck in most cases, especially at night. I use 50 or 60LB most nights and 80LB sometimes.
However, I like fluorocarbon also for its better stiffness over mono, its ability to sink faster than mono due to its higher density, and pound for pound its better abrasive-resistance - I think you can drop down one LB size with fluoro over mono most times (like 60Lb to 50LB...).
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